Structures of Protonated Methyl Phenols in Antimony Pentafluoride-Fluorosulfuric Acid at - 60 °C
John W. Larsen
; Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37916, U.S.A . and Institute Rueter Boskovic, 41001 Zagreb, Croatia, Yugoslavia
Mirjana Eckert-Maksić
; Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37916, U.S.A . and Institute Rueter Boskovic, 41001 Zagreb, Croatia, Yugoslavia
APA 6th Edition Larsen, J.W. i Eckert-Maksić, M. (1973). Structures of Protonated Methyl Phenols in Antimony Pentafluoride-Fluorosulfuric Acid at - 60 °C. Croatica Chemica Acta, 45 (3), 503-510. Preuzeto s https://hrcak.srce.hr/197021
MLA 8th Edition Larsen, John W. i Mirjana Eckert-Maksić. "Structures of Protonated Methyl Phenols in Antimony Pentafluoride-Fluorosulfuric Acid at - 60 °C." Croatica Chemica Acta, vol. 45, br. 3, 1973, str. 503-510. https://hrcak.srce.hr/197021. Citirano 06.03.2021.
Chicago 17th Edition Larsen, John W. i Mirjana Eckert-Maksić. "Structures of Protonated Methyl Phenols in Antimony Pentafluoride-Fluorosulfuric Acid at - 60 °C." Croatica Chemica Acta 45, br. 3 (1973): 503-510. https://hrcak.srce.hr/197021
Harvard Larsen, J.W., i Eckert-Maksić, M. (1973). 'Structures of Protonated Methyl Phenols in Antimony Pentafluoride-Fluorosulfuric Acid at - 60 °C', Croatica Chemica Acta, 45(3), str. 503-510. Preuzeto s: https://hrcak.srce.hr/197021 (Datum pristupa: 06.03.2021.)
Vancouver Larsen JW, Eckert-Maksić M. Structures of Protonated Methyl Phenols in Antimony Pentafluoride-Fluorosulfuric Acid at - 60 °C. Croatica Chemica Acta [Internet]. 1973 [pristupljeno 06.03.2021.];45(3):503-510. Dostupno na: https://hrcak.srce.hr/197021
IEEE J.W. Larsen i M. Eckert-Maksić, "Structures of Protonated Methyl Phenols in Antimony Pentafluoride-Fluorosulfuric Acid at - 60 °C", Croatica Chemica Acta, vol.45, br. 3, str. 503-510, 1973. [Online]. Dostupno na: https://hrcak.srce.hr/197021. [Citirano: 06.03.2021.]
Sažetak The site of protonation of a series of methyl substituted phenols
in 11.5 mole '°/o SbF5 in HS03F was determined using NMR spectrometry.
Some substituent effects are explicable without invoking
specific salvation. Protonation para to the hydroxy group was
favored, but was blocked completely in all but one case by .a
p-alkyl group. In para substituted phenols, ortho protonation predominated.
Both oxygen and ring protonation were observed for
the p-cresol.