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Direct Chemical Reduction of Triphenylcarbinol to Triphenylmethane

Maurice M. Kreevoy ; Chemical Dynamics Laboratory, University of Minnesota, Minneapolis, Minnesota, U .S.A.
David C. Johnston ; Chemical Dynamics Laboratory, University of Minnesota, Minneapolis, Minnesota, U .S.A.

Puni tekst: engleski, pdf (4 MB) str. 511-514 preuzimanja: 137* citiraj
APA 6th Edition
Kreevoy, M.M. i Johnston, D.C. (1973). Direct Chemical Reduction of Triphenylcarbinol to Triphenylmethane. Croatica Chemica Acta, 45 (3), 511-514. Preuzeto s https://hrcak.srce.hr/197022
MLA 8th Edition
Kreevoy, Maurice M. i David C. Johnston. "Direct Chemical Reduction of Triphenylcarbinol to Triphenylmethane." Croatica Chemica Acta, vol. 45, br. 3, 1973, str. 511-514. https://hrcak.srce.hr/197022. Citirano 08.03.2021.
Chicago 17th Edition
Kreevoy, Maurice M. i David C. Johnston. "Direct Chemical Reduction of Triphenylcarbinol to Triphenylmethane." Croatica Chemica Acta 45, br. 3 (1973): 511-514. https://hrcak.srce.hr/197022
Harvard
Kreevoy, M.M., i Johnston, D.C. (1973). 'Direct Chemical Reduction of Triphenylcarbinol to Triphenylmethane', Croatica Chemica Acta, 45(3), str. 511-514. Preuzeto s: https://hrcak.srce.hr/197022 (Datum pristupa: 08.03.2021.)
Vancouver
Kreevoy MM, Johnston DC. Direct Chemical Reduction of Triphenylcarbinol to Triphenylmethane. Croatica Chemica Acta [Internet]. 1973 [pristupljeno 08.03.2021.];45(3):511-514. Dostupno na: https://hrcak.srce.hr/197022
IEEE
M.M. Kreevoy i D.C. Johnston, "Direct Chemical Reduction of Triphenylcarbinol to Triphenylmethane", Croatica Chemica Acta, vol.45, br. 3, str. 511-514, 1973. [Online]. Dostupno na: https://hrcak.srce.hr/197022. [Citirano: 08.03.2021.]

Sažetak
BH3cN- has been found to be a moderately efficient trapping
agent for triphenylmethyl cations, roughly comparable to chloride
ion. Since BH3CN- is moderately resistant to acid hydrolysis, it can
trap triphenylmethyl cations generated by treatment of triphenylcarbinol
with HCl in 25% water - 750/o tetrahydrofuran. A quantitative
yield of triphenylmetharie, based on unrecovered tripheny~carbinol,
can be obtained, but the process is inefficient in its use of
BH3CN- because of the competing hydrolysis.

Hrčak ID: 197022

URI
https://hrcak.srce.hr/197022

Posjeta: 176 *