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The Mechanism of Electro-Reduction of Chromate in Molten LiCl-KCl

H. A. Laitinen ; Roger Adams Laboratory, The University of Illinois, Urbana-Champaign, Illinois 61801, U.S.A.
L. R. Lieto ; Roger Adams Laboratory, The University of Illinois, Urbana-Champaign, Illinois 61801, U.S.A.

Puni tekst: engleski, pdf (9 MB) str. 275-281 preuzimanja: 60* citiraj
APA 6th Edition
Laitinen, H.A. i Lieto, L.R. (1972). The Mechanism of Electro-Reduction of Chromate in Molten LiCl-KCl. Croatica Chemica Acta, 44 (2), 275-281. Preuzeto s https://hrcak.srce.hr/197273
MLA 8th Edition
Laitinen, H. A. i L. R. Lieto. "The Mechanism of Electro-Reduction of Chromate in Molten LiCl-KCl." Croatica Chemica Acta, vol. 44, br. 2, 1972, str. 275-281. https://hrcak.srce.hr/197273. Citirano 06.03.2021.
Chicago 17th Edition
Laitinen, H. A. i L. R. Lieto. "The Mechanism of Electro-Reduction of Chromate in Molten LiCl-KCl." Croatica Chemica Acta 44, br. 2 (1972): 275-281. https://hrcak.srce.hr/197273
Harvard
Laitinen, H.A., i Lieto, L.R. (1972). 'The Mechanism of Electro-Reduction of Chromate in Molten LiCl-KCl', Croatica Chemica Acta, 44(2), str. 275-281. Preuzeto s: https://hrcak.srce.hr/197273 (Datum pristupa: 06.03.2021.)
Vancouver
Laitinen HA, Lieto LR. The Mechanism of Electro-Reduction of Chromate in Molten LiCl-KCl. Croatica Chemica Acta [Internet]. 1972 [pristupljeno 06.03.2021.];44(2):275-281. Dostupno na: https://hrcak.srce.hr/197273
IEEE
H.A. Laitinen i L.R. Lieto, "The Mechanism of Electro-Reduction of Chromate in Molten LiCl-KCl", Croatica Chemica Acta, vol.44, br. 2, str. 275-281, 1972. [Online]. Dostupno na: https://hrcak.srce.hr/197273. [Citirano: 06.03.2021.]

Sažetak
When chromate ion is electro-reduced in molten LiCl- KCl
in the presence of Mg (II), Zn (II) or Ni (II), the product is typically
of composition LixMyCr04 , in which X + 2 Y = 5. Variations
in composition accompany variations is experimental conditions,
except in the case of Zn(II), for which X = 1 and Y = · 2.
With Co (II), the product is either LixCoyCr04 or Co2Cr04 or a
mixture of the two, depending upon the conditions. A mechanism
involving a first two-electron reduction followed by a competition
between further one-electron reduction and an internal chemical
redox reaction accounts -satisfactorily for the variation of product
with changes in experimental conditions.

Hrčak ID: 197273

URI
https://hrcak.srce.hr/197273

Posjeta: 114 *