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Original scientific paper
https://doi.org/10.5562/cca3247
Great Efficiency of Nucleosides as Organizing Tools
Sonja Merkaš
; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France
Souhaila Bouatra
; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France
Régis Rein
; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France
Ivo Piantanida
; Laboratory of Supramolecular and Nucleoside Chemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Mladen Žinić
; Laboratory of Supramolecular and Nucleoside Chemistry, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Nathalie Solladié
; CNRS, 205 route de Narbonne, 31077 Toulouse, France; Université de Toulouse, UPS, INPT, 31077 Toulouse, France
| Fulltext: english, pdf (6 MB) | pages 595-602 | cite | |
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APA 6th Edition Merkaš, S., Bouatra, S., Rein, R., Piantanida, I., Žinić, M. & Solladié, N. (2017). Great Efficiency of Nucleosides as Organizing Tools. Croatica Chemica Acta, 90 (4), 595-602. https://doi.org/10.5562/cca3247 MLA 8th Edition Merkaš, Sonja, et al. "Great Efficiency of Nucleosides as Organizing Tools." Croatica Chemica Acta, vol. 90, no. 4, 2017, pp. 595-602. https://doi.org/10.5562/cca3247. Accessed 23 Jan. 2021. Chicago 17th Edition Merkaš, Sonja, Souhaila Bouatra, Régis Rein, Ivo Piantanida, Mladen Žinić and Nathalie Solladié. "Great Efficiency of Nucleosides as Organizing Tools." Croatica Chemica Acta 90, no. 4 (2017): 595-602. https://doi.org/10.5562/cca3247 Harvard Merkaš, S., et al. (2017). 'Great Efficiency of Nucleosides as Organizing Tools', Croatica Chemica Acta, 90(4), pp. 595-602. https://doi.org/10.5562/cca3247 Vancouver Merkaš S, Bouatra S, Rein R, Piantanida I, Žinić M, Solladié N. Great Efficiency of Nucleosides as Organizing Tools. Croatica Chemica Acta [Internet]. 2017 [cited 2021 January 23];90(4):595-602. https://doi.org/10.5562/cca3247 IEEE S. Merkaš, S. Bouatra, R. Rein, I. Piantanida, M. Žinić and N. Solladié, "Great Efficiency of Nucleosides as Organizing Tools", Croatica Chemica Acta, vol.90, no. 4, pp. 595-602, 2017. [Online]. https://doi.org/10.5562/cca3247 |
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Abstracts
Bis-porphyrins with flexible linkers such as uridine or 2’-deoxyuridin pre-organize in a face-to-face conformation and form stable sandwich complexes with bidentate base such as DABCO. The gain in stability can be even greater when a dinucleotide linker is used. Such pre-organization increases the association constant by one to two orders of magnitude when compared to the one of DABCO with a reference porphyrin. Comparison with rigid tweezers shows a better efficiency of nucleosidic dimers. The choice of rigid spacers is not the only way to pre-organize bis-porphyrins, and well-chosen nucleosidic linkers offer an interesting option for the synthesis of such devices.
This work is licensed under a Creative Commons Attribution 4.0 International License.
Keywords
porphyrins; tweezers; nucleosides; molecular recognition
Hrčak ID: 198181
URI
https://hrcak.srce.hr/198181
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