Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles
Marija Alešković
; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia
Mladena Glavaš
; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia
Marina Šekutor
; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia
Kata Mlinarić-Majerski
orcid.org/0000-0001-6282-1662
; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia
APA 6th Edition Alešković, M., Glavaš, M., Šekutor, M. i Mlinarić-Majerski, K. (2017). Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles. Croatica Chemica Acta, 90 (4), 637-643. https://doi.org/10.5562/cca3248
MLA 8th Edition Alešković, Marija, et al. "Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles." Croatica Chemica Acta, vol. 90, br. 4, 2017, str. 637-643. https://doi.org/10.5562/cca3248. Citirano 27.01.2021.
Chicago 17th Edition Alešković, Marija, Mladena Glavaš, Marina Šekutor i Kata Mlinarić-Majerski. "Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles." Croatica Chemica Acta 90, br. 4 (2017): 637-643. https://doi.org/10.5562/cca3248
Harvard Alešković, M., et al. (2017). 'Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles', Croatica Chemica Acta, 90(4), str. 637-643. https://doi.org/10.5562/cca3248
Vancouver Alešković M, Glavaš M, Šekutor M, Mlinarić-Majerski K. Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles. Croatica Chemica Acta [Internet]. 2017 [pristupljeno 27.01.2021.];90(4):637-643. https://doi.org/10.5562/cca3248
IEEE M. Alešković, M. Glavaš, M. Šekutor i K. Mlinarić-Majerski, "Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles", Croatica Chemica Acta, vol.90, br. 4, str. 637-643, 2017. [Online]. https://doi.org/10.5562/cca3248
Sažetak Two new adamantane anion receptors with amidopyrrole side arms were prepared and their anion binding ability in DMSO solutions with TBA salts (Cl–, AcO– and H2PO4–) was investigated by UV/Vis spectroscopy. After calculating the corresponding association constants of receptor-anion complexes, it became apparent that only one amidopyrrole side arm was engaged in complexation. These experimental findings were rationalized using computational tools and the binding mode was proposed. In addition to the found 1 : 1 stoichiometry, we showed that the studied receptors bind oxo-anions (H2PO4– and AcO–) more strongly than spherical halogenide (Cl–) anions.