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https://doi.org/10.5562/cca3248

Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles

Marija Alešković ; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia
Mladena Glavaš ; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia
Marina Šekutor ; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia
Kata Mlinarić-Majerski   ORCID icon orcid.org/0000-0001-6282-1662 ; Department of Organic Chemistry and Biochemistry, Ruđer Bošković Institute, Bijenička cesta 54, P.O. Box 180, 10002, Zagreb, Croatia

Puni tekst: engleski, pdf (2 MB) str. 637-643 preuzimanja: 199* citiraj
APA 6th Edition
Alešković, M., Glavaš, M., Šekutor, M. i Mlinarić-Majerski, K. (2017). Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles. Croatica Chemica Acta, 90 (4), 637-643. https://doi.org/10.5562/cca3248
MLA 8th Edition
Alešković, Marija, et al. "Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles." Croatica Chemica Acta, vol. 90, br. 4, 2017, str. 637-643. https://doi.org/10.5562/cca3248. Citirano 13.11.2019.
Chicago 17th Edition
Alešković, Marija, Mladena Glavaš, Marina Šekutor i Kata Mlinarić-Majerski. "Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles." Croatica Chemica Acta 90, br. 4 (2017): 637-643. https://doi.org/10.5562/cca3248
Harvard
Alešković, M., et al. (2017). 'Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles', Croatica Chemica Acta, 90(4), str. 637-643. https://doi.org/10.5562/cca3248
Vancouver
Alešković M, Glavaš M, Šekutor M, Mlinarić-Majerski K. Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles. Croatica Chemica Acta [Internet]. 2017 [pristupljeno 13.11.2019.];90(4):637-643. https://doi.org/10.5562/cca3248
IEEE
M. Alešković, M. Glavaš, M. Šekutor i K. Mlinarić-Majerski, "Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles", Croatica Chemica Acta, vol.90, br. 4, str. 637-643, 2017. [Online]. https://doi.org/10.5562/cca3248

Sažetak
Two new adamantane anion receptors with amidopyrrole side arms were prepared and their anion binding ability in DMSO solutions with TBA salts (Cl–, AcO– and H2PO4–) was investigated by UV/Vis spectroscopy. After calculating the corresponding association constants of receptor-anion complexes, it became apparent that only one amidopyrrole side arm was engaged in complexation. These experimental findings were rationalized using computational tools and the binding mode was proposed. In addition to the found 1 : 1 stoichiometry, we showed that the studied receptors bind oxo-anions (H2PO4– and AcO–) more strongly than spherical halogenide (Cl–) anions.

Creative Commons License This work is licensed under a Creative Commons Attribution 4.0 International License.

Ključne riječi
anion receptors; adamantane amidopyrroles; binding assessment

Hrčak ID: 198488

URI
https://hrcak.srce.hr/198488

Posjeta: 306 *