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https://doi.org/10.5562/cca3333

Alkali Salts of Nitranilic and Cyanochloranilic Acids

Valentina Milašinović   ORCID icon orcid.org/0000-0001-6761-876X ; Ruđer Bošković Institute, Bijenička cesta 54, HR-10000, Zagreb, Croatia
Krešimir Molčanov   ORCID icon orcid.org/0000-0002-4328-3181 ; Ruđer Bošković Institute, Bijenička cesta 54, HR-10000, Zagreb, Croatia

Puni tekst: engleski, pdf (10 MB) str. 177-186 preuzimanja: 473* citiraj
APA 6th Edition
Milašinović, V. i Molčanov, K. (2018). Alkali Salts of Nitranilic and Cyanochloranilic Acids. Croatica Chemica Acta, 91 (2), 177-186. https://doi.org/10.5562/cca3333
MLA 8th Edition
Milašinović, Valentina i Krešimir Molčanov. "Alkali Salts of Nitranilic and Cyanochloranilic Acids." Croatica Chemica Acta, vol. 91, br. 2, 2018, str. 177-186. https://doi.org/10.5562/cca3333. Citirano 09.03.2021.
Chicago 17th Edition
Milašinović, Valentina i Krešimir Molčanov. "Alkali Salts of Nitranilic and Cyanochloranilic Acids." Croatica Chemica Acta 91, br. 2 (2018): 177-186. https://doi.org/10.5562/cca3333
Harvard
Milašinović, V., i Molčanov, K. (2018). 'Alkali Salts of Nitranilic and Cyanochloranilic Acids', Croatica Chemica Acta, 91(2), str. 177-186. https://doi.org/10.5562/cca3333
Vancouver
Milašinović V, Molčanov K. Alkali Salts of Nitranilic and Cyanochloranilic Acids. Croatica Chemica Acta [Internet]. 2018 [pristupljeno 09.03.2021.];91(2):177-186. https://doi.org/10.5562/cca3333
IEEE
V. Milašinović i K. Molčanov, "Alkali Salts of Nitranilic and Cyanochloranilic Acids", Croatica Chemica Acta, vol.91, br. 2, str. 177-186, 2018. [Online]. https://doi.org/10.5562/cca3333

Sažetak
Series of novel alkali salts of nitranilic acid (3,6-dinitro-2,5-dihydroxyquinone) and cyanochloranilic acid (3-cyano-6-chloro-2,5-dihydroxyquinone), and also of neutral cyanochloranilic acid dihydrate, were prepared and their structures were studied. The nitranilate dianion revealed a considerable conformational flexibility of nitro groups. Steric and inductive effects exerted by different substituents (nitro, cyano and chloro) and their influence on molecular geometry and crystal packing are discussed.

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Ključne riječi
nitranilic acid; cyanochloranilic acid; quinone; crystal structure

Hrčak ID: 201072

URI
https://hrcak.srce.hr/201072

Posjeta: 769 *