hrcak mascot   Srce   HID

Izvorni znanstveni članak

Secondary Hydrogen Isotope Effects. VII. Ethanolysis Rates of 1,1-Dimethylallyl-3,3-d2 Chloride and 3,3-Dimethylallyl-1,1-d2 Chloride

V. Belanić-Lipovac ; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
S. Borčić ; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
D. E. Sunko ; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia

Puni tekst: engleski, pdf (6 MB) str. 61-65 preuzimanja: 33* citiraj
APA 6th Edition
Belanić-Lipovac, V., Borčić, S. i Sunko, D.E. (1965). Secondary Hydrogen Isotope Effects. VII. Ethanolysis Rates of 1,1-Dimethylallyl-3,3-d2 Chloride and 3,3-Dimethylallyl-1,1-d2 Chloride. Croatica Chemica Acta, 37 (2), 61-65. Preuzeto s https://hrcak.srce.hr/208216
MLA 8th Edition
Belanić-Lipovac, V., et al. "Secondary Hydrogen Isotope Effects. VII. Ethanolysis Rates of 1,1-Dimethylallyl-3,3-d2 Chloride and 3,3-Dimethylallyl-1,1-d2 Chloride." Croatica Chemica Acta, vol. 37, br. 2, 1965, str. 61-65. https://hrcak.srce.hr/208216. Citirano 25.02.2021.
Chicago 17th Edition
Belanić-Lipovac, V., S. Borčić i D. E. Sunko. "Secondary Hydrogen Isotope Effects. VII. Ethanolysis Rates of 1,1-Dimethylallyl-3,3-d2 Chloride and 3,3-Dimethylallyl-1,1-d2 Chloride." Croatica Chemica Acta 37, br. 2 (1965): 61-65. https://hrcak.srce.hr/208216
Harvard
Belanić-Lipovac, V., Borčić, S., i Sunko, D.E. (1965). 'Secondary Hydrogen Isotope Effects. VII. Ethanolysis Rates of 1,1-Dimethylallyl-3,3-d2 Chloride and 3,3-Dimethylallyl-1,1-d2 Chloride', Croatica Chemica Acta, 37(2), str. 61-65. Preuzeto s: https://hrcak.srce.hr/208216 (Datum pristupa: 25.02.2021.)
Vancouver
Belanić-Lipovac V, Borčić S, Sunko DE. Secondary Hydrogen Isotope Effects. VII. Ethanolysis Rates of 1,1-Dimethylallyl-3,3-d2 Chloride and 3,3-Dimethylallyl-1,1-d2 Chloride. Croatica Chemica Acta [Internet]. 1965 [pristupljeno 25.02.2021.];37(2):61-65. Dostupno na: https://hrcak.srce.hr/208216
IEEE
V. Belanić-Lipovac, S. Borčić i D.E. Sunko, "Secondary Hydrogen Isotope Effects. VII. Ethanolysis Rates of 1,1-Dimethylallyl-3,3-d2 Chloride and 3,3-Dimethylallyl-1,1-d2 Chloride", Croatica Chemica Acta, vol.37, br. 2, str. 61-65, 1965. [Online]. Dostupno na: https://hrcak.srce.hr/208216. [Citirano: 25.02.2021.]

Sažetak
Primary aind tertiary dimethylallyl chlorides deuterated at
either the alpha or gamma pos~tion were prepared a:nd subjected
to e.thanolysis. A kinetic isotope effect (kt1/kn) of 1.20 was observed
in the reaction of the primary isomer while rthe tertiary chloride
reacted at the same rate as the undeuterated analog,. The absence
of an isotope effect in the latter case is explained by the lack
of sp3 - sp2 rehybridization of the carbon-deuterium bonds in the
rate determining step.

Hrčak ID: 208216

URI
https://hrcak.srce.hr/208216

Posjeta: 70 *