Croatica Chemica Acta, Vol. 35 No. 1, 1963.
Izvorni znanstveni članak
Secondary Hydrogen Isotopes Effects. VI . Acetolysis Rate of Cyclopentyl-3,3,4,4-d4 Tosylate
S. Borčić
; Institute »Rudjer Boskovic«, Zagreb , Croatia, Yugoslavia
Sažetak
The synthesis 6f cyclopentyl-3,3,4,4-d4 p-toluenesulfonate is
described. The acetolysis rate constant of this compound at 50.00
was determined. With the help of the IBM 7090 computer a
kinetic isotope effect (kH/kD) of about 0.95 was found to occur. This
small rate increase is interpreted as possibly due to the + I
effect of d euterium.
Ključne riječi
Hrčak ID:
208362
URI
Datum izdavanja:
22.4.1963.
Posjeta: 400 *