Croatica Chemica Acta, Vol. 91 No. 4, 2018.
Izvorni znanstveni članak
https://doi.org/10.5562/cca3454
Frequency Response Analysis of a Nonstationary System: Electrochemical Transition of Polyaniline
Katja Magdić Košiček
; Division for Marine and Environmental Research, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Višnja Horvat-Radošević
; Division for Marine and Environmental Research, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Krešimir Kvastek
; Division for Marine and Environmental Research, Ruđer Bošković Institute, Bijenička c. 54, HR-10000 Zagreb, Croatia
Sažetak
In this work, impedance spectra of polyaniline film electrode recorded at some redox transition potentials have been corrected for nonstationarity by application of Stoynov's 4-D method. The procedure consisted from: a) conventional measurements of a series of impedance spectra under strictly same experimental conditions, which are accompanied by monitoring of real operating time intervals for measurement of each particular impedance spectrum of the series, b) determination of functional dependence(s) between iso-frequency impedance values and operating time, and c) calculations of instantaneous IS for the time instant of the beginning of the first IS measurement. Comparison between measured and instantaneous impedance spectra, and also between their individual impedance parameter values pointed toward significant differences in charge transfer and transport resistance values. The results suggest that erroneous (either underestimated or overestimated) charge transfer and transport resistance values will be obtained if measured impedance spectra were not corrected for nonstationarity.
This work is licensed under a Creative Commons Attribution 4.0 International License.
Ključne riječi
nonstationary impedance spectra; instantaneous impedance spectra; polyaniline film electrode; redox transition states
Hrčak ID:
217072
URI
Datum izdavanja:
30.12.2018.
Posjeta: 1.303 *