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Izvorni znanstveni članak
https://doi.org/10.5562/cca3485
Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry
Dijana Jadreško
; Division for Marine and Environmental Research, Ruđer Bošković Institute, P.O. Box 180, HR-10002 Zagreb, Croatia
| Puni tekst: engleski, pdf (5 MB) | str. 95-102 | citiraj | |
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APA 6th Edition Jadreško, D. (2019). Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry. Croatica Chemica Acta, 92 (1), 95-102. https://doi.org/10.5562/cca3485 MLA 8th Edition Jadreško, Dijana. "Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry." Croatica Chemica Acta, vol. 92, br. 1, 2019, str. 95-102. https://doi.org/10.5562/cca3485. Citirano 01.03.2021. Chicago 17th Edition Jadreško, Dijana. "Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry." Croatica Chemica Acta 92, br. 1 (2019): 95-102. https://doi.org/10.5562/cca3485 Harvard Jadreško, D. (2019). 'Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry', Croatica Chemica Acta, 92(1), str. 95-102. https://doi.org/10.5562/cca3485 Vancouver Jadreško D. Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry. Croatica Chemica Acta [Internet]. 2019 [pristupljeno 01.03.2021.];92(1):95-102. https://doi.org/10.5562/cca3485 IEEE D. Jadreško, "Simulation of Alternative Differential Multi-pulse Voltammetry. Evaluation of the Electrochemical Reversibility by the Voltammogram Symmetry", Croatica Chemica Acta, vol.92, br. 1, str. 95-102, 2019. [Online]. https://doi.org/10.5562/cca3485 |
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Sažetak
A theoretical analysis of reversible and kinetically controlled electrode reactions in conditions of alternative differential multi-pulse voltammetry (ADMPV) is presented. The degree of reversibility, as well as symmetry of the electron transfer reaction, can be estimated by visual inspection of the ADMP voltammogram. The values of electron transfer coefficient and the standard rate constant of a simple electrode reaction Ox + ne− ⇄ Red, can be determined from the slope of linear dependence of the peak currents ratio on the logarithm of pulse duration. The criteria for recognition of reversible and kinetically controlled electrode reactions by alternative differential multi-pulse voltammetry are given.
This work is licensed under a Creative Commons Attribution 4.0 International License.
Ključne riječi
alternative differential multi-pulse voltammetry; excitation signal; kinetics; symmetry; theory
Hrčak ID: 221404
URI
https://hrcak.srce.hr/221404
Moj profil
Srce