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The Use of Silver Phenyl Benzyl Phosphate for the Synthesis of Monophenyl Esters of Phosphatidic Acids

P. E. Verkade ; Laboratory of Organic Chemistry, Technical University, Delft, Netherlands
L. J. Stegerhoek ; Laboratory of Organic Chemistry, Technical University, Delft, Netherlands
S. Mostert Pzn ; Laboratory of Organic Chemistry, Technical University, Delft, Netherlands

Sažetak

Hessel, Morton, Todd, and Verkade have shown that dibenzyl esters of a-glycerophosphatidic acids I (D = acyl group), when shaken at room temperature in an ethanolic medium with hydrogen under slightly more than atmospheric pressure in the presence of a palladium/ active carbon catalyst according to Verkade, Cohen, and Vroege are smoothly hydrogenolyzed; 2 moles of hydrogen per mole of ester are rapidly absorbed, resulting in the formation of the corresponding phosphatidic acids and toluene.

Ključne riječi

Hrčak ID:

246322

URI

https://hrcak.srce.hr/246322

Datum izdavanja:

30.12.1957.

Posjeta: 318 *