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The influence of the chemical structure on the properties of molecularly imprinted crosslinked polymers

Ana ERCEG KUZMIĆ ; INA-Industrija nafte d.d., Research and Development Sector, Zagreb
Radivoje VUKOVIĆ ; INA-Industrija nafte d.d., Research and Development Sector, Zagreb
Grozdana BOGDANIĆ ; INA-Industrija nafte d.d., Research and Development Sector, Zagreb
Dragutin FLEŠ ; INA-Industrija nafte d.d., Research and Development Sector, Zagreb

Puni tekst: hrvatski, pdf (175 KB) str. 176-182 preuzimanja: 370* citiraj
APA 6th Edition
ERCEG KUZMIĆ, A., VUKOVIĆ, R., BOGDANIĆ, G. i FLEŠ, D. (2005). Utjecaj kemijske strukture na svojstva molekulski tiskanih umreženih polimera. Polimeri, 26 (4), 176-182. Preuzeto s https://hrcak.srce.hr/3142
MLA 8th Edition
ERCEG KUZMIĆ, Ana, et al. "Utjecaj kemijske strukture na svojstva molekulski tiskanih umreženih polimera." Polimeri, vol. 26, br. 4, 2005, str. 176-182. https://hrcak.srce.hr/3142. Citirano 20.10.2020.
Chicago 17th Edition
ERCEG KUZMIĆ, Ana, Radivoje VUKOVIĆ, Grozdana BOGDANIĆ i Dragutin FLEŠ. "Utjecaj kemijske strukture na svojstva molekulski tiskanih umreženih polimera." Polimeri 26, br. 4 (2005): 176-182. https://hrcak.srce.hr/3142
Harvard
ERCEG KUZMIĆ, A., et al. (2005). 'Utjecaj kemijske strukture na svojstva molekulski tiskanih umreženih polimera', Polimeri, 26(4), str. 176-182. Preuzeto s: https://hrcak.srce.hr/3142 (Datum pristupa: 20.10.2020.)
Vancouver
ERCEG KUZMIĆ A, VUKOVIĆ R, BOGDANIĆ G, FLEŠ D. Utjecaj kemijske strukture na svojstva molekulski tiskanih umreženih polimera. Polimeri [Internet]. 2005 [pristupljeno 20.10.2020.];26(4):176-182. Dostupno na: https://hrcak.srce.hr/3142
IEEE
A. ERCEG KUZMIĆ, R. VUKOVIĆ, G. BOGDANIĆ i D. FLEŠ, "Utjecaj kemijske strukture na svojstva molekulski tiskanih umreženih polimera", Polimeri, vol.26, br. 4, str. 176-182, 2005. [Online]. Dostupno na: https://hrcak.srce.hr/3142. [Citirano: 20.10.2020.]

Sažetak
The present paper describes the synthesis of monomers N-methacryl-N,N’-dicyclohexylurea (MA-DCU) and N-methacryl-N,N’-diisopropylurea (MA-DiPrU) and their polymerization with ethylene glycol dimethacrylate (EDMA). Polymerization were carried out in butanone by using dibenzoyl-peroxide (Bz2O2) up to high conversion. All prepared copolymers are insoluble in common organic solvent. Crosslinked copolymers decompose thermally at temperatures from 180 °C to 450 °C under the separation of cyclohexylisocyanate (C6H11NCO) or isopropylisocyanate (C3H7NCO) at temperature between 180 °C and 250 °C. Residues after the removal of isocyanate are thermally stable nanoporous crosslinked copolymers of methacryl-cyclohexylamide (MA-CHA) or methacryl-isopropylamide (MA-iPrA) with EDMA, which decompose by a one-step mechanism between 280 °C and 450 °C.

Nonporous model copolymers of MA-CHA and MA-iPrA with EDMA were also prepared in order to compare their properties with the properties of corresponding nanoporous copolymers.

Ključne riječi
chemical structure; molecularly imprinted copolymers; imprinted copolymers; nanoporous copolymers; nonporous copolymers; poly(N-methacryl-N,N’-dicyclohexylurea-co-ethylene-glycol dimethacrylate); poly(N-methacryl-N,N’- diisopropylurea -co-ethylene-glycol

Hrčak ID: 3142

URI
https://hrcak.srce.hr/3142

[hrvatski]

Posjeta: 711 *