Izvorni znanstveni članak

Graphite Electrode Modified with a New Phenothiazine Derivative and with Carbon Nanotubes for NADH Electrocatalytic Oxidation

D. Gligor ; “Babes-Bolyai” University, Department of Physical Chemistry, 11 Arany Janos St., 400028 Cluj-Napoca, Romania
C. Varodi ; “Babes-Bolyai” University, Department of Physical Chemistry, 11 Arany Janos St., 400028 Cluj-Napoca, Romania
L. M. Muresan ; “Babes-Bolyai” University, Department of Physical Chemistry, 11 Arany Janos St., 400028 Cluj-Napoca, Romania

Sažetak

The electrochemical behavior of a modified electrode obtained by immobilization of single-walled carbon nanotubes onto a graphite electrode modified with a new phenothiazine derivative, bis-phenothiazin-3-yl methane (BPhM), G/BPhM-CNT, has been
evaluated and compared with BPhM adsorbed on graphite electrode (G/BPhM). The G/BPhM-CNT electrode presents improved performances for NADH electrocatalytic oxidation in comparison with G/BPhM electrode, expressed by: (i) a significant increase of
electrocatalytic rate constant (kobs,[NADH] 0) for NADH oxidation (856.32 L mol–1 s–1 for G/BPhM-CNT and 51.63 L mol–1 s–1 for G/BPhM, in phosphate buffer, pH 7); (ii) the obtained amperometric sensors for NADH detection present increase sensitivity (S = 6.9
mA L mol–1 for G/BPhM-CNT and S = 0.55 mA L mol–1 for G/BPhM, pH 7).

Ključne riječi

Phenothiazine derivative; carbon nanotubes; NADH

Hrčak ID:

55021

URI

https://hrcak.srce.hr/55021

Datum izdavanja:

1.7.2010.

Posjeta: 970 *