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Reaction Kinetics in Intracellular Environments: The Two Proposed Models Yield Qualitatively Different Predictions

Željko Bajzer
Miljenko Huzak
Kevin Neff
Franklyn G. Prendergast

Puni tekst: engleski, pdf (208 KB) str. 437-444 preuzimanja: 542* citiraj
APA 6th Edition
Bajzer, Ž., Huzak, M., Neff, K. i Prendergast, F.G. (2006). Reaction Kinetics in Intracellular Environments: The Two Proposed Models Yield Qualitatively Different Predictions. Croatica Chemica Acta, 79 (3), 437-444. Preuzeto s https://hrcak.srce.hr/5649
MLA 8th Edition
Bajzer, Željko, et al. "Reaction Kinetics in Intracellular Environments: The Two Proposed Models Yield Qualitatively Different Predictions." Croatica Chemica Acta, vol. 79, br. 3, 2006, str. 437-444. https://hrcak.srce.hr/5649. Citirano 08.03.2021.
Chicago 17th Edition
Bajzer, Željko, Miljenko Huzak, Kevin Neff i Franklyn G. Prendergast. "Reaction Kinetics in Intracellular Environments: The Two Proposed Models Yield Qualitatively Different Predictions." Croatica Chemica Acta 79, br. 3 (2006): 437-444. https://hrcak.srce.hr/5649
Harvard
Bajzer, Ž., et al. (2006). 'Reaction Kinetics in Intracellular Environments: The Two Proposed Models Yield Qualitatively Different Predictions', Croatica Chemica Acta, 79(3), str. 437-444. Preuzeto s: https://hrcak.srce.hr/5649 (Datum pristupa: 08.03.2021.)
Vancouver
Bajzer Ž, Huzak M, Neff K, Prendergast FG. Reaction Kinetics in Intracellular Environments: The Two Proposed Models Yield Qualitatively Different Predictions. Croatica Chemica Acta [Internet]. 2006 [pristupljeno 08.03.2021.];79(3):437-444. Dostupno na: https://hrcak.srce.hr/5649
IEEE
Ž. Bajzer, M. Huzak, K. Neff i F.G. Prendergast, "Reaction Kinetics in Intracellular Environments: The Two Proposed Models Yield Qualitatively Different Predictions", Croatica Chemica Acta, vol.79, br. 3, str. 437-444, 2006. [Online]. Dostupno na: https://hrcak.srce.hr/5649. [Citirano: 08.03.2021.]

Sažetak
A recently proposed model by Schnell and Turner for reaction kinetics in environments crowded by macromolecules is applied to elementary bimolecular binding. It is found that it leads to an unusual equilibrium constant equal to zero. The progress curves are qualitatively different from the prediction of a model based on a non-integer (fractal) power law proposed earlier by Savageau. In the case of the Michaelis-Menten reaction, the two models predict qualitatively similar progress curves and identical equilibrium concentrations. The two models are investigated analytically and numerically, and their differences are discussed in regard to possible validation of the models by use of experimental data.

Ključne riječi
macromolecular crowding; law of mass action; fractal kinetics; enzymatic reactions

Hrčak ID: 5649

URI
https://hrcak.srce.hr/5649

Posjeta: 795 *