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The Potential of Fe-exchanged Y Zeolite as a Heterogeneous Fenton-type Catalyst for Oxidative Degradation of Reactive Dye in Water

M. Aleksić ; Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, Zagreb, Croatia
N. Koprivanac ; Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, Zagreb, Croatia
A. Lončarić Božić ; Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, Zagreb, Croatia
H. Kušić ; Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, Zagreb, Croatia

Puni tekst: engleski, pdf (3 MB) str. 309-319 preuzimanja: 465* citiraj
APA 6th Edition
Aleksić, M., Koprivanac, N., Lončarić Božić, A. i Kušić, H. (2010). The Potential of Fe-exchanged Y Zeolite as a Heterogeneous Fenton-type Catalyst for Oxidative Degradation of Reactive Dye in Water. Chemical and Biochemical Engineering Quarterly, 24 (3), 309-319. Preuzeto s https://hrcak.srce.hr/59068
MLA 8th Edition
Aleksić, M., et al. "The Potential of Fe-exchanged Y Zeolite as a Heterogeneous Fenton-type Catalyst for Oxidative Degradation of Reactive Dye in Water." Chemical and Biochemical Engineering Quarterly, vol. 24, br. 3, 2010, str. 309-319. https://hrcak.srce.hr/59068. Citirano 22.09.2019.
Chicago 17th Edition
Aleksić, M., N. Koprivanac, A. Lončarić Božić i H. Kušić. "The Potential of Fe-exchanged Y Zeolite as a Heterogeneous Fenton-type Catalyst for Oxidative Degradation of Reactive Dye in Water." Chemical and Biochemical Engineering Quarterly 24, br. 3 (2010): 309-319. https://hrcak.srce.hr/59068
Harvard
Aleksić, M., et al. (2010). 'The Potential of Fe-exchanged Y Zeolite as a Heterogeneous Fenton-type Catalyst for Oxidative Degradation of Reactive Dye in Water', Chemical and Biochemical Engineering Quarterly, 24(3), str. 309-319. Preuzeto s: https://hrcak.srce.hr/59068 (Datum pristupa: 22.09.2019.)
Vancouver
Aleksić M, Koprivanac N, Lončarić Božić A, Kušić H. The Potential of Fe-exchanged Y Zeolite as a Heterogeneous Fenton-type Catalyst for Oxidative Degradation of Reactive Dye in Water. Chemical and Biochemical Engineering Quarterly [Internet]. 2010 [pristupljeno 22.09.2019.];24(3):309-319. Dostupno na: https://hrcak.srce.hr/59068
IEEE
M. Aleksić, N. Koprivanac, A. Lončarić Božić i H. Kušić, "The Potential of Fe-exchanged Y Zeolite as a Heterogeneous Fenton-type Catalyst for Oxidative Degradation of Reactive Dye in Water", Chemical and Biochemical Engineering Quarterly, vol.24, br. 3, str. 309-319, 2010. [Online]. Dostupno na: https://hrcak.srce.hr/59068. [Citirano: 22.09.2019.]

Sažetak
The study aimed to investigate the potential of Fe-exchanged zeolites of Y-type as a catalyst in heterogeneous Fenton-type processes for the degradation of model organic pollutant, reactive azo dye C.I. Reactive Blue 137, in water. The research work was directed to investigate the influence of process variables, such as FeY catalyst dosage, Fenton reagent ratio, and initial operating pH on the efficiency of the treatment process. The performance of the studied heterogeneous process was compared with corresponding
homogeneous Fenton-type processes, while the influence of UV light on both heterogeneous and homogeneous processes was investigated as well. The results of FeY catalyst characterization indicate that the iron content is mainly built into the inner zeolite
micropores providing the benefit to zeolite stability and activity of the catalyst. Based on the decolorization and the mineralization degree of RB137 model wastewater, the overall process efficiency was estimated. Homogeneous and heterogeneous Fenton processes
yielded similar decolorization and mineralization, but the concentration of Fe ions in the bulk after treatment was significantly lower in the latter case. Moreover, the use of the heterogeneous catalyst allowed the UV-assisted process to be operated at milder pH conditions, pH 5, while the most suitable pH for the dark heterogeneous process showed to be pH 3.

Ključne riječi
Heterogeneous catalysis; Fenton-type process; FeY; zeolites; model wastewater; UV irradiation; degradation mechanisms

Hrčak ID: 59068

URI
https://hrcak.srce.hr/59068

Posjeta: 715 *