Izvorni znanstveni članak

https://doi.org/10.5562/cca2304

Borane Polyhedra as Building Blocks for Unknown but Potentially Isolatable New Molecules – Extensions based on Computations of the Known B18H22 Isomers

Josep M. Oliva ; Instituto de Química-Física “Rocasolano”, CSIC, 28006 Madrid, Spain
Juanjo Rué ; Instituto de Ciencias Matemáticas (CSIC – UAM – UC3M – UCM), Universidad Autónoma de Madrid, 28049 Madrid, Spain
John D. Kennedy ; Institute of Inorganic Chemistry of the AS CR, v.v.i., 250 68 Husinec-Řež, Czech Republic;The School of Chemistry of the University of Leeds, Leeds LS2 9JT, UK
Vladimir R. Rosenfeld ; Texas A&M University, Galveston, TX 77553, USA

Sažetak

Known borane polyhedral cluster characteristics can be used for predicting new architectural
constructs. We propose additional structures derived from B18H22 : three positional isomers different from
the well-known anti-B18H22 and syn-B18H22 boranes. We have also derived two new cyclic structures
based on the condensation of borane pentagonal pyramids and bipyramids. The concatenation of polyhedral
borane molecules is also considered from a mathematical point of view. (doi: 10.5562/cca2304)

Ključne riječi

boranes; bond; B18H22; quantum chemistry; mathematical chemistry

Hrčak ID:

112785

URI

https://hrcak.srce.hr/112785

Datum izdavanja:

16.12.2013.

Posjeta: 2.515 *