Skoči na glavni sadržaj

Croatica Chemica Acta, Vol. 61 No. 2, 1988.

Izvorni znanstveni članak

Infrared and Raman Spectroscopy of the Dirhodium Tetraacetate Complexes Rh2(O2CCH3)4, Rh2(18O2CCH3)4, Rh2(O2CCD3)4 and Rh2(O2CCH3)4(H2O)2

Robin J. H. Clark ; Christopher Ingold Laboratories University College London 20 Gordon Street London WC1H 0AJ, U. K.
Andrew J. Hempleman ; Christopher Ingold Laboratories University College London 20 Gordon Street London WC1H 0AJ, U. K.

Puni tekst: engleski pdf 7.189 Kb

str. 313-329

preuzimanja: 733

citiraj

Sažetak

The infrared (3500-50 cm-I), and Raman (3550-30 cm-I)
spectra of the dirhodium tetraacetate species Rh2(02CCHs)4,
Rh2(IB02CCHs)4, Rh2(02CCDS)4, and Rh2(02CCHs)4(H20)2 have been recorded and the key bands assigned, The oxygen-18 and deuteration studies, in particular, assisted with ma king the important band assignments for the anhydrous complex, for which 11 (RhRh)
occurs at 355-351 cm-I, and 11 (RhO) at 389-319 cm-I (Raman) and
398-341 cm-I (infrared). The band attributed to 11 (RhRh) is typically
intense, sharp, and relatively insensitive to either IBO_ or CDs-substitution. Thus 11 (RhRh) shifts only 4 cm-Ion either IBO
or CDs substitution whereas 11 (RhO) shifts 4-6 cm-I in the Raman
and 3-7 cm-I in the infrared spectra on IBO substitution but 12
cm-I in the Raman and 11-18 cm-I in the infrared spectra on CDs
substitution. Some preliminary isotopic work for the complex
Rh2(02CCHS)4(H20l2 is also presented.

Ključne riječi

Hrčak ID:

175904

URI

https://hrcak.srce.hr/175904

Datum izdavanja:

30.9.1988.

Posjeta: 1.244 *