Croatica Chemica Acta, Vol. 70 No. 2, 1997.
Izvorni znanstveni članak
Microstructural Properties of Leucite-type Glass-ceramics for Dental Use
Svetozar Musić
; Ruder Bošković Institute, P. O. Box 1016, 10001 Zagreb, Croatia
Jasenka Živko-Babić
; Faculty of Dentistry, University of Zagreb, 10000 Zagreb, Croatia
Ketij Mehulić
; Faculty of Dentistry, University of Zagreb, 10000 Zagreb, Croatia
Mira Ristić
; Ruder Bošković Institute, P. O. Box 1016, 10001 Zagreb, Croatia
Stanko Popović
; Ruder Bošković Institute, P. O. Box 1016, 10001 Zagreb, Croatia
Krešimir Furić
; Ruder Bošković Institute, P. O. Box 1016, 10001 Zagreb, Croatia
Dunja Selinger-Kocijan
; INA-NAFTAPLIN, 10000 Zagreb, Croatia
Stojan Ćelap
; INA-NAFTAPLIN, 10000 Zagreb, Croatia
Tomislav Ivaniš
; Faculty of Dentistry, University of Zagreb, 10000 Zagreb, Croatia
Sažetak
Microstructure of leucite-type dental glass-ceramics was investigated
using X-ray diffraction, Fourier transform infrared spectroscopy, laser
Raman spectroscopy, scanning electron microscopy and energy dispersive X-ray spectrometry. The main features of the FT-IR and laser Raman spectra were similar to those of silicate glasses containing Al3+ or other M3+(M = metal) as network forming ions. Two weak IR bands at 640 and 543 cm-1 were typical of all leucite glass-ceramics. These IR bands disappeared with the conversion of leucite glass-ceramics to the glass state. The laser Raman spectrum ofleucitetype glass exhibited one unusual band centred approximately at 4600 cm-I possessing the fluorescenceiluminescence spectral feature together with two luminescence sharp peaks at 5037 and 5007 cm-I. The effects of quenching (cooling) on the morphological and chemical properties of leucite-type dental glass-ceramics were monitored.
Ključne riječi
Hrčak ID:
176968
URI
Datum izdavanja:
1.5.1997.
Posjeta: 1.143 *