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Nonactin and the Coupe du Roi

Kurt Mislow ; Department of Chemistry, Princeton University, Princeton, New Jersey 08544, U.S.A.


Puni tekst: engleski pdf 2.181 Kb

str. 353-358

preuzimanja: 431

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Sažetak

The macrolide antibiotic nonactin is the first example of a natural product with S4 symmetry. It is now pointed out that the synthesis of nonactin by dimerization-cyclization of (-)-nonactyl- (+ )-nonactic acid, reported by Ulrich Schmidt in 1975, is also the first example of a chemical combination of two homochiral molecules to give an achiral product.

Ključne riječi

Hrčak ID:

178018

URI

https://hrcak.srce.hr/178018

Datum izdavanja:

6.3.1986.

Posjeta: 916 *