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Zero-Field Splitting Parameters D of Macrocyclic Systems

H. Vogler ; MPI fur Medizinische Forschung, Abteilung Organische Chemie, Jahnstr. 29, D-6900 Heidelberg, Germany


Puni tekst: engleski pdf 5.606 Kb

str. 667-673

preuzimanja: 454

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Sažetak

The triplet zero-field splitting parameters D of [4n]- and
[4n + 2]-annulenes are calculated within a n-model. The dependence
of D on n and the degree of bond lengths alternation is
compared with that of ground state properties like magnetic ring
currents. Furthermore it is shown that corannulenes which consist
of two concentric perimeters with connecting radial bonds cannot
be regarded as macrocyclic annulenoid systems in the triplet state.

Ključne riječi

Hrčak ID:

194493

URI

https://hrcak.srce.hr/194493

Datum izdavanja:

25.1.1981.

Posjeta: 902 *