Croatica Chemica Acta, Vol. 44 No. 1, 1972.
Izlaganje sa skupa
Electrochemical Generation of Solvated Electrons and Hydrogen Evolution in Hexamethylphosphortriamide
L. I. Krishtalik
; Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow, USSR
N. M. Alpatova
; Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow, USSR
M. G. Fomicheva
; Institute of Electrochemistry, Academy of Sciences of the USSR, Moscow, USSR
Sažetak
Electrolysis experiments with rotating disc electrodes of copper,
amalgamated copper, and platinum in anhydrous hexamethylphosphortriamide are described. It is shown that the generation
of solvated electrons is a primary process. In the same
solutions (0.2 M LiCl + 0.09 to 0.20 M HCl) hydrogen evolution
occurs as a direct proton discharge step and not through a reaction
with the solvated electron(s).
Ključne riječi
Hrčak ID:
197280
URI
Datum izdavanja:
15.5.1972.
Posjeta: 870 *