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Original scientific paper

Synthesis of Pyridazine Derivatives. XVII. Some Reactions on 2-Phenylimidazo(1,2-b )pyridazines

B. Stanovnik ; Department of Chemistry, University of Ljubljana, Ljubljana, Slovenia, Yugoslavia
M. Tišler ; Department of Chemistry, University of Ljubljana, Ljubljana, Slovenia, Yugoslavia


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Abstract

The behavior of 2-phenylimidazo(l,2-b)pyridazines in some
electrophilic and nucleophilic subs.titution reactions has been
examined. It has been found that besides the expected electrophilic
substitution at position 3 of the imidazo-(1,2-b)pyridazine
ring, upon nitration a second nitro group enters the phenyl group
on para position as evident from an examination of the NMR
spectrum. Hydrazinolysis of a 3,6-dihalo derivative proceeded preferentially
at position 6.

Keywords

Hrčak ID:

208058

URI

https://hrcak.srce.hr/208058

Publication date:

15.5.1968.

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