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The Behavior of 2-Acetamido-2-deoxy-o-galactose with Isopropenyl Acetate in the Presence of p-Toluenesulfonic Acid. Formation of an Unsaturated Aminosugar Derivative

N. Pravdić ; National Institute of Arthritis and Metabolic Diseases, National Institutes of Health, Public Health Service, U.S. Department of Health
H . G. Fletcher, Jr. ; Education, and Welfare, Bethesda, Maryland 20014, U.S. A.

Sažetak

Treatment of 2-acetamido-2-deoxy-n-galactose (III) with isopropenyl
acetate and p-toluenesulfonic acid gives 2-(n-glycero-1,2-
-diacetoxyethyl)-4-(N-acetylacetamido) furan (II), the anomeric 1,3,
4,6-te tra-O-acety 1- 2-(N -acetylacetamido )-2-d eoxy-o-gala ctopyranoses (IV and V), a mixture of the anomeric 1,3,5,6-te tra-0-acetyl-2- -(N-acetylacetamido) -2- deoxy-o-galactofuranoses (VII) and 1,4,6 - -tri -O-acetyl-2-(N-acetylacetamido)-2 ,3-dideoxy-o-threo-hex-2-enopyranose (X) . The anomeric 2-acetamido-1,3,4,6 -tetra-O-acetyl-2- -deo xy-n-galactopyranoses (VI) were also d etected ; they may be
primary products or artifacts arising from IV and V by spontaneous
de-N-acetylation in the course of the chromatography w hich was
used.

Ključne riječi

Hrčak ID:

208092

URI

https://hrcak.srce.hr/208092

Datum izdavanja:

10.8.1967.

Posjeta: 747 *