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Equivalent Orbitals of NH, NH2 and NH3

N. Trinajstić ; Chemical Laboratory, the University of Sussex, Brighton, England


Puni tekst: engleski pdf 5.082 Kb

str. 287-291

preuzimanja: 584

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Sažetak

Equivalent orbitals of NH, NH2 and NH3 have been d erived
using the procedure based on the criterion of maximum overlap,
from LCAO SCF MO's by Higuchi. Lone pair EO obtained from
such a method contain no contribution from the hydrogen (1 s)
orbitals, in agreement with results based on Pople's method. The
differences in s a nd p character of the N - H bonds and the lone
pairs on nitrogen of NH, NH2 and NH3 have been investigated using
these equivalent orbitals.

Ključne riječi

Hrčak ID:

208148

URI

https://hrcak.srce.hr/208148

Datum izdavanja:

28.12.1966.

Posjeta: 1.189 *