Original scientific paper
Temporal evolution of intermetallic diffuse band spectra
Irena Labazan
; Institute of Physics, P.O.Box 304, HR-10000 Zagreb, Croatia
Davorka Azinović
; Institute of Physics, P.O.Box 304, HR-10000 Zagreb, Croatia
Srećko Gogić
; Institute of Physics, P.O.Box 304, HR-10000 Zagreb, Croatia
Slobodan Milošević
; Institute of Physics, P.O.Box 304, HR-10000 Zagreb, Croatia
Abstract
LiZn and LiCd vapour mixtures prepared in the heat-pipe oven are irradiated with pulsed excimer laser emission at 308 nm. Temporal evolution of the fluorescence spectra is observed showing that different processes occur such as multiphoton excitation, collisional energy transfer, photochemical reaction, relaxation etc. Temporal change of the LiZn and LiCd blue-green diffuse bands spectral shape is observed and interpreted in terms of previous spectral simulations. The effective lifetimes of different spectral features are determined.
Keywords
LiZn – LiCd vapour mixtures; pulsed excimer laser irradiation; temporal evolution of fluorescence spectra; multiphoton excitation; collisional energy transfer; photochemical reaction; relaxation; effective lifetimes
Hrčak ID:
300897
URI
Publication date:
1.3.1999.
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