Original scientific paper

Crystal Structure of Hexacyanoferrato(III)bis(µ-cyano){1,3-bis-[(4-methyl-5-imidazol-1-yl)ethylideneamino]propan-2-olcopper(II) Hexacyanoferrato(III)-µ-cyano-1,3-bis[(4-methyl-5-imidazol-1-yl)-ethylideneamino]propan-2-olcuprate(II) Tetradecahydrate

La-Sheng Long ; Department of Chemistry, Xiamen University, Xiamen 361005, China
Yan-Ping Ren ; Department of Chemistry, Xiamen University, Xiamen 361005, China
Rong-Bing Huang ; Department of Chemistry, Xiamen University, Xiamen 361005, China
Lan-Sun Zheng ; Department of Chemistry, Xiamen University, Xiamen 361005, China
Xiao-Ming Chen ; Department of Chemistry, Zhongshan University, Guangzhou 510275, China
Seik Weng Ng ; Institute of Postgraduate Studies, University of Malaya, 50603 Kuala Lumpur, Malaysia

Abstract

The crystal structure of hexacyanoferrato(III)bis(µ-cyano){1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propan-2-ol}copper(II) hexacyanoferrato(III)-µ-cyano-{1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propan-2-ol}cuprate(II) tetradecahydrate consists of trinuclear cations and dinuclear anions whose copper atoms show square pyramidal and iron atoms octahedral coordination. The cations and anions are linked by hydrogen bonds involving 14 lattice water molecules in a network architecture. Crystals of the C₅₁H₈₂Cu₃Fe₂N₃₀O₁₇ belong to the triclinic P1̅ space group [a = 13.700(2), b = 13.881(2), c = 21.431(3) Å; α = 76.96(1), β = 83.07(1), γ = 74.70(1)°].

Keywords

crystal structure; copper hexacyanatoferrate(III) complex

Hrčak ID:

103053

URI

https://hrcak.srce.hr/103053

Publication date:

30.4.2003.

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