Original scientific paper

Determination of Optimal Conditions to Achieve Maximal Response at Maximal Repeatability in FIA-AMZ Experiment through a Mathematical Modelling Approach

Milko Novič ; National Institute of Chemistry, Hajdrihova 19, 1001 Ljubljana, Slovenia
Marjana Novič orcid.org/0000-0002-4243-2181 ; National Institute of Chemistry, Hajdrihova 19, 1001 Ljubljana, Slovenia

Abstract

The determination of optimal experimental conditions in flow injection analysis asynchronous merging zone technique (FIA-AMZ) on the basis of a mathematical model is proposed. An improved commutator enabling reagent addition with minimal frontal dispersion is used for the simultaneous determination of two species,
Fe2+ and Fe3+ ions. The mathematical model used to simulate the detector response is based on a bell-shaped function. The model is well suited for the fitting of symmetrical as well as for very asymmetrical detector responses, reflecting different dispersion of the sample plugs. The influence of the frontal dispersion of the reagent, asymmetrically added to the sample plug, is studied using the proposed model. A measure for an optimal ratio between the sensitivity and repeatability is described on the basis of the parameters obtained from the simulations of the experimental curves obtained for different dispersions.

Keywords

flow injection analysis; AMZ; optimization; modelling; Fe²⁺; Fe³⁺

Hrčak ID:

127535

URI

https://hrcak.srce.hr/127535

Publication date:

3.6.2002.

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