Croatica Chemica Acta, Vol. 65 No. 1, 1992.
Original scientific paper
Stretching Vibrations of Amino Group and Inter/Intramolecular Hydrogen Bond in Anilines
Gleb S. Denisov
; Institute of Physics, Leningrad State University, Leningrad, Petrodvorcz, USSR 19S904
Ljudmila A. Kuzina
; Institute of Physics, Leningrad State University, Leningrad, Petrodvorcz, USSR 19S904
Dmitrij N. Shchepkin
; Institute of Physics, Leningrad State University, Leningrad, Petrodvorcz, USSR 19S904
Abstract
The IR spectra of or//io-substituled anilines with intramolecular hydrogen bond NH- • -O and their complexes with protonoacccptors have been studied in solution. The enthalpy of a complex with a symmetrically perturbed amino group was taken as a definition of the intramolecular bond strength; it increases in the scries of substitutes NO2
Keywords
Hrčak ID:
137259
URI
Publication date:
15.6.1992.
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