Original scientific paper

Electronic Structure and Spectra of Thiolo- and Dithiocarbamates. MO Treatment

Maher M. Hamed ; Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt
Abdel Ghany El-Kourashy ; Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt
Hussien Moustafa ; Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt
Rifaat Hilal ; Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt

Abstract

Electronic absorption spectra of some thiolo- and dithiocarbamates are reported. The observed spectra have been computer deconvoluted and accurate peak parameters have been determined. Assignment of the observed bands has been facilitated by MO computations. Comparison with the spectra of carbamates enabled prediction of the effect of replacing oxygen by sulphur on the electronic structure of carbamates.

Keywords

Hrčak ID:

137318

URI

https://hrcak.srce.hr/137318

Publication date:

15.10.1991.

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