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Croatica Chemica Acta, Vol. 61 No. 4, 1988.

Original scientific paper

Mass Spectral Study of Anthrone

D. Srzić ; Ruđer Bošković Institute, Zagreb, Croatia, Yugoslavia
S. M. Shevchenko ; Ruđer Bošković Institute, Zagreb, Croatia, Yugoslavia
L. Klasinc ; Ruđer Bošković Institute, Zagreb, Croatia, Yugoslavia

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Abstract

The electron impact induced fragmentation of anthrone and
its 10,1O-dideuterated analogue has been studied in the mass
spectrometer using low and high resolution, as well as ion kinetic
energy measurements. The most important process observed in
the mass spectra is 105sof CO from the molecular ions with formation
of ions of possible fluorenyl cation structure. Such ions, as shown earlier, undergo extensive hydrogen scrambling. In agreement with a fluorenyl cation structure, statistical loss of hydrogen in the fragmentation of anthrone is observed.

Keywords

Hrčak ID:

176006

URI

https://hrcak.srce.hr/176006

Publication date:

30.12.1988.

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