Original scientific paper

Testing the Conformal Ionic Solution Theory for the Additive Ternary Molten Salt System

Ivan J. Gal ; Institute of Chemistry, Faculty of Science, University of Belgrade, Belgrade, Yugoslavia
Istvan J. Zsigrai ; Institute of Chemistry, Faculty of Science, University of Novi Sad, Novi Sad, Yugoslavia

Abstract

The conformal ionic solution theory predicts excess chemical potentials of the components in a ternary additive molten salt system, if suitable thermodynamic data on the three subsidiary binary molten salt systems are available. The excess chemical potential of AgCl in the system AgCl-LiCl-KCl has been calculated theoretically, using the published data on binary molten salt systems AgCl-LiCI, AgCl-KCl and LiCl-KCl. The calculated values are compared with the corresponding data based
on emf measurements in the ternary system, and discussed with respect to the use of the theory in the thermodynamics of additive molten salt systems.

Keywords

Hrčak ID:

176389

URI

https://hrcak.srce.hr/176389

Publication date:

23.12.1987.

Visits: 903 *