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Croatica Chemica Acta, Vol. 54 No. 1, 1981.

Original scientific paper

Gravimetric Determination of Molybdenum(VI) Employing N-Hydroxy-N-p-Chlorophenyl-N' -(2-Methyl-4-Chlorophenyl) Benzamidine Hydrochloride

R. S. Kharsan ; Department of Chemistry, Ravishankar University, Raipur 492 010 M. P. India
R. K. Mishra ; Department of Chemistry, Ravishankar University, Raipur 492 010 M. P. India

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Abstract

The use of N-hydroxy-N-p-chlorophenyl-N'-(2-methyl-4-chlorophenyl)
benzamidine hydrochloride abbreviated as HCPMCPBH
as a highly selective chelating agent for molybdenum has been
investigated. The dioxomolybdenum complex Mo02(C20H1 5N20Ch)2
is quantitatively precipitated at pH = 2.8-6.6. As the complex can
not be washed free of excess reagent, the dried complex is ignited
at 500-550 °c to Mo03 for final determination. Most of the usual
ions do not interfere. The method has also been applied for the
determination of molybdenum in ferro-molybdenum and molybdenum
ores.

Keywords

Hrčak ID:

194435

URI

https://hrcak.srce.hr/194435

Publication date:

15.3.1981.

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