Original scientific paper

Some Platinum Group. Metal Complexes of Substituted Thiosemicarbazones

M. C. Jain ; Department of Chemistry, Meerut College, Meerut-250001, India
R. K. Sharma ; Department of Chemistry, Meerut College, Meerut-250001, India
P. C. Jain ; Department of Chemistry, Meerut College, Meerut-250001, India

Abstract

Complexes of Ru(III), Rh(III) and Pt(IV) with 1-salicyl-4-
-benzylamidothiosemicarbazone (SBTS) and 1-(a-)furyl-4-benzylamidothiosemicarbazone
(FBTS) have been prepared and their
stereochemistry proposed on the basis of magnetic and electronic
spectral studies. The ruthenium(llI) complexes reveal an
anomalous magnetic behaviour which may possibly be attributed
to a large spin-orbit coupling. The rhodium(III) and platinum(IV)
complexes of SBTS conform to the octahedral geometry. Relevant
ligan-field parameters, wherever possible, have been calculated.
Infra-red studies indicate the (S, N) bidentate nature of FBTS,
whereas SBTS acts as a (S, N, 0) tridentate ligand.

Keywords

Hrčak ID:

195936

URI

https://hrcak.srce.hr/195936

Publication date:

8.2.1979.

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