Original scientific paper

Spectrophotometric Determination of Titanium as a Mixed Thiocyanate-1-pheny 1-2-methy 1-3-hydroxy-4-pyridone Complex

B. Tamhina ; Laboratory of Analytical Chemistry, Faculty of Science, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
V. Vojković ; Laboratory of Analytical Chemistry, Faculty of Science, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia
M. J. Herak ; Laboratory of Analytical Chemistry, Faculty of Science, University of Zagreb, 41000 Zagreb, Croatia, Yugoslavia

Abstract

The extn. of titanium(IV) thiocyanate complex by 1-phenyl-2-
-methyl-3-hydroxy-4-pyridone(HX) dissolved in chloroform has
been investigated from hydrochloric and sulphuric acid solns. The
extd. complex has the ratio Ti : SCN : HX 1 : 2 : 2. Chloroform solns.
follow Beer's law and are stable for at least 24 h. A sensitive and
reproducible spectrophotometric detn. of titanium is possible. The
molar absorptivity of the method is 26 500 1 mo1-1 cm-1 at 365 nm.
Few metals interfere, and their sepn. is discussed.

Keywords

Hrčak ID:

196351

URI

https://hrcak.srce.hr/196351

Publication date:

20.7.1977.

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