Croatica Chemica Acta, Vol. 48 No. 4, 1976.
Conference paper
Bond Formation in Electrosorbates
J. W. Schultze
; Institut fur Physikalische Chemie und Quantenchemie der Freien Universitat Berlin
Abstract
The electrosorption valency y is defined and its meaning is
thoroughly discussed. Exiptl. dent. of y is demonstrated for systems
Au/Bi3+ and Pt/Cu2+. It is found that for homonuclear ions in aq.
solns. the ratio y/z, where z stands for Nernst valency, is successfully
correlated with the electro.negativity difference I XM - Xs I of
the electrode metal M and the sorbate S. For small electronegativity
differences, y/z •is close to unity indicating large covalency.
Bond formation in electrosorbates in non-aq. solvents and at single
crystal plames of various orientations are briefly discussed.
Keywords
Hrčak ID:
196451
URI
Publication date:
22.12.1976.
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