Croatica Chemica Acta, Vol. 35 No. 3, 1963.
Original scientific paper
Electrokinetic Studies in Disperse Systems. VII. Ion Exchange and the Electrokinetic Potential of Precipitates of Silver Iodide
V . Pravdić
; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
Z. Jović
; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
M . Mirnik
; Institute »Ruder Boskovic«, Zagreb, Croatia, Yugoslavia
Abstract
A systematic study of the influence of exchange of ions on
the surface of silver iodide precipitates on the elektrokinetic
potential (EKP) was undertaken. Examples of the exchange o:f
ions of valencies 1 :2, 1 :3, 1 :4, 2 :4 and 3 :4 are given. At higher
activity of potential determining ions in solution, at pl= 3, larger
changes in the EKP were measured. At the same pl effects of specific
adsorption o:f Th4+ were found. The conclusion is drawn, that
the exchange of ions at the surface bears no direct, simple relation
to the EKP.
Keywords
Hrčak ID:
208342
URI
Publication date:
30.11.1963.
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