Original scientific paper

Secondary Hydrogen Isotopes Effects. V. Internal Rearrangement in the Acetolysis of Deuterium Labeled Cyclopropylmethyl Benzenesulfonates

S. Borčić ; Institute »Ruder Boskovic«, Zagreb , Croatia, Yugoslavia
D. E. Sunko ; Institute »Ruder Boskovic«, Zagreb , Croatia, Yugoslavia

Abstract

The acetolysis vs. internal rearrangement products ratio was
determined for cyclopropylmethyl, cyclopropylmethyi-1 ,1-dii and
-3,3-d2 benzenesulfonate and was found to remain constant within
the experimental error. The results confirm that both concurrent
reactions proceed through a common intermediate in which the bond
between the carbonium ion and the leaving group must be pureiy
ionic.

Keywords

Hrčak ID:

208443

URI

https://hrcak.srce.hr/208443

Publication date:

10.10.1961.

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