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https://doi.org/10.5562/cca2247

Formation of Oxide Phases in the System Pr-Fe-O

Mira Ristić orcid id orcid.org/0000-0003-0033-9840 ; Ruđer Bošković Institute, Bijenička cesta 54, P. O. Box 180, Zagreb, HR-10002, Croatia
Stanko Popović ; Department of Physics, Faculty of Science, University of Zagreb, Zagreb, HR-10000, Croatia
Svetozar Musić ; Ruđer Bošković Institute, Bijenička cesta 54, P. O. Box 180, Zagreb, HR-10002, Croatia


Puni tekst: engleski pdf 3.317 Kb

str. 281-285

preuzimanja: 1.557

citiraj


Sažetak

The formation of oxide phases at 900 °C in the system Fe2O3-“Pr2O3” was investigated. With a decrease in the molar fraction of Fe2O3 a corresponding increase in PrFeO3 was observed. For equal molar fractions of Fe2O3 and “Pr2O3” the formation of PrFeO3 and very small fractions of α-Fe2O3 plus an addi¬tional oxide phase, which could not be identified with certainty, were observed. With further increase in “Pr2O3” fraction the praseodymium oxides Pr6O11 and PrO2 started to become dominant in the phase com¬position. The small fraction (< 0.02) of the same unidentified oxide phase was also obtained when Pr(OH)3 was calcined in air at 900 °C; this was probably a mixture of other praseodymium oxides with different average oxidation numbers of Pr. The results of XRD, 57Fe Mössbauer and FT-IR spectroscopies are discussed. (doi: 10.5562/cca2247)

Ključne riječi

α-Fe2O3; PrFeO3; praseodymium oxides

Hrčak ID:

111311

URI

https://hrcak.srce.hr/111311

Datum izdavanja:

20.11.2013.

Posjeta: 2.750 *