Croatica Chemica Acta, Vol. 87 No. 3, 2014.
Izvorni znanstveni članak
https://doi.org/10.5562/cca2381
Direct and Facile Synthesis of Acyl Isothiocyanates from Carboxylic Acids Using Trichloroisocyanuric Acid/Triphenylphosphine System
Najmeh Entezari
; Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran
Batool Akhlaghinia
orcid.org/0000-0002-9940-5045
; Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran
Hamed Rouhi-Saadabad
; Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran
Sažetak
A mild, efficient, and practical method for one-step synthesis of alkanoyl and aroyl isothiocyanates from carboxylic acids using a safe and inexpensive mixed reagent, trichloroisocyanuric acid/triphenyl¬phosphine is described at room temperature. Availability of the reagents and easy workup of the reaction make this method attractive for organic chemists.
Ključne riječi
acyl isothiocyanates, carboxylic acids, trichloroisocyanuric acid (TCCA), triphenylphosphine (TPP), potassium thiocyanate
Hrčak ID:
130427
URI
Posjeta: 3.312 *