Croatica Chemica Acta, Vol. 87 No. 3, 2014.
Izvorni znanstveni članak
https://doi.org/10.5562/cca2381
Direct and Facile Synthesis of Acyl Isothiocyanates from Carboxylic Acids Using Trichloroisocyanuric Acid/Triphenylphosphine System
Najmeh Entezari
; Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran
Batool Akhlaghinia
orcid.org/0000-0002-9940-5045
; Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran
Hamed Rouhi-Saadabad
; Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran
Sažetak
A mild, efficient, and practical method for one-step synthesis of alkanoyl and aroyl isothiocyanates from carboxylic acids using a safe and inexpensive mixed reagent, trichloroisocyanuric acid/triphenyl¬phosphine is described at room temperature. Availability of the reagents and easy workup of the reaction make this method attractive for organic chemists.
Ključne riječi
acyl isothiocyanates; carboxylic acids; trichloroisocyanuric acid (TCCA); triphenylphosphine (TPP); potassium thiocyanate
Hrčak ID:
130427
URI
Datum izdavanja:
18.11.2014.
Posjeta: 4.387 *