Izvorni znanstveni članak

Photoelectron Spectra and Conformational Behaviour of 3-Isopropenylcyclopropene Derivatives

Mirjana Eckert-Maksić ; Department of Chemistry, Ruder Bošković Institute, P.O.B. 1016, 10000 Zagreb, Croatia
Ljiljana Maksimović ; Department of Chemistry, Ruder Bošković Institute, P.O.B. 1016, 10000 Zagreb, Croatia
Irena Zrinski ; Department of Chemistry, Ruder Bošković Institute, P.O.B. 1016, 10000 Zagreb, Croatia
Tamara S. Kuznetsova ; Department of Chemistry, Moscow State University, Moscow, Russia
Nikolai S. Zefirov ; Department of Chemistry, Moscow State University, Moscow, Russia

Sažetak

The electronic and molecular structure of a series of 1,2-dialkyl (1-3) and 1,2-diphenyl-3-isopropenylcyclopropene (4) have been investigated by means of He(I) photoelectron spectroscopy and ab initio MO calculations. The changes in the lowest energy ionization along the series are interpreted in terms of conformotionally dependent conjugative interaction between the isopropenyl group and cyclopropenyl ring.

Ključne riječi

Hrčak ID:

135988

URI

https://hrcak.srce.hr/135988

Datum izdavanja:

2.12.1996.

Posjeta: 1.082 *