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Solvation of Ions. V. Silver(I) Ion in Water-Dimethyl Sulfoxide Mixtures

Warren L. Reynolds ; Department of Chemistry, 207 Pleasant Street SE, University of Minnesota, Minneapolis, MN 55455-0431, USA
Steven Davis ; Department of Applied Mathematics, Cornell University, Ithaca, NY 14853, USA

Sažetak

The Gibbs' free energies of transfer of silver(I) ion, AtG° (Ag+), from water to water-dimethyl sulfoxide (W/D) binary mixtures have been used to obtain the distribution of solvated ions, [AgW/Dfc]+, present over the mole fraction range from 0.05 to 0.95 for dimethyl sulfoxide. Major species were [AgWsD]+, [AgW1gD]+, [AgW3D2]+, [AgWD3]+, [AgDg]+, [AgWD9]+, [AgD14]+. The water-rich solvated ions were present only at small dimethyl sulfoxide concentrations.

Ključne riječi

Hrčak ID:

135989

URI

https://hrcak.srce.hr/135989

Datum izdavanja:

2.12.1996.

Posjeta: 830 *