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The Structure of Zeolite and Aluminophosphate Molecular Sieves

Venčeslav Kaučič ; National Institute of Chemistry and University of Ljubljana P. O. Box 30, 61115 Ljubljana, Slovenia


Puni tekst: engleski pdf 7.091 Kb

str. 241-261

preuzimanja: 1.556

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Sažetak

Zeolites and other molecular sieves are microporous crystalline solids whose main uses are in catalysis, ion-exchange reactions and as adsorbents. Their crystalline structures and different ways of identification of molecular sieve structure are reviewed, together with a short introduction into the catalytic activity of these materials. Synthesis and structural overview of aluminophosphates, a new and fast-growing family of microporous materials, are presented and strategy for introducing different metal atoms into aluminophosphate framework is discussed. These chemical framework modifications lead to a broad range of structure types and offer a nearly unlimited number of design parameters for the tailoring of catalityc and adsorptive properties of aluminophosphate materials. Our results in the areas of synthesis and X-ray diffraction structural characterization of metal-substituted aluminophosphates are reviewed.

Ključne riječi

Hrčak ID:

136889

URI

https://hrcak.srce.hr/136889

Datum izdavanja:

1.8.1994.

Posjeta: 2.180 *