Croatica Chemica Acta, Vol. 64 No. 4, 1991.
Original scientific paper
Solvation of Chloropentaamminecobalt(III) Ion in Water-Dimethyl Sulfoxide Mixtures
Warren L. Reynolds
; University of Minnesota, Chemistry Department, 207 Pleasant Street, S.E., Minneapolis, Minnesota 55455, USA
Steven Davis
; University of Minnesota, Chemistry Department, 207 Pleasant Street, S.E., Minneapolis, Minnesota 55455, USA
Mira Glavaš
; Faculty of Science, University of Sarajevo, 71000 Sarajevo, Yugoslavia
Abstract
The composition of the solvation shell of chloropentaamminecobalt(III) was investigated for water + dimethyl sulfoxide solvent mixtures using the Gibbs free energy of transfer and PMR solvent line broadening data. Strong evidence was found for the formation of solvated species with a unique dimethyl sulfoxide molecule in the solvation shell, which substantiates a previous conclusion concerning the existence of such species.
Keywords
Hrčak ID:
137277
URI
Publication date:
29.2.1992.
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