Croatica Chemica Acta, Vol. 64 No. 4, 1991.
Original scientific paper
The Use of Phenanthrenequinonedioxime Supported on Naphthalene for the Preconcentration and Determination of Copper in Alloys and Human Hair
Bal Krishan Puri
; Department of Chemistry, Indian Institute of Technology, Hauz Khas, New Delhi-110016, India
Masatada Satake
; Faculty of Engineering, Fukui University, Fukui 910, Japan
Jing Ri Lee
; Faculty of Engineering, Fukui University, Fukui 910, Japan
Abstract
Solid chelating compound, phenanthrenequinonedioxime (PQDO), supported on naphthalene, provides a simple, rapid and economical means of preconcentrating copper in alloys and biological samples. Copper forms a chelate with PQDO supported on naphthalene in the column at pH 1.8—8.4. The metal complex and naphthalene are dissolved out of the column with 5 ml of dimethylformamide (DMF) and the absorbance is measured by an atomic absorption spectrometer at 324 nm. A calibration curve is linear over the concentration range 0.5—12.0 fig of copper in 5 ml of the final solution. The preconcentration factor is 80. The sensitivity for 1% absorption is 0.039 fig/ml (0.153 fig/ml for the direct AAS method from the aqueous medium). The method has been used for the determination of copper in various standard alloys and biological samples.
Keywords
Hrčak ID:
137278
URI
Publication date:
29.2.1992.
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