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C-C Bond Lengths and Hybridization in some Cyclopropane Derivatives. GED Structure Studies of 1-Methyl-1-tert-butyl-cyclopropane and 1-Methyl-1-iso-propyl-cyclopropane

Marit Trætteberg ; Department of Chemistry, University of Trondheim, AVH, N-7055 Trondheim, Norway
Wolfgang Lüttke ; Organisch-Chemisches Institut der Universitat Gottingen, Tammannstrasse 4, D-3400 Gottingen, Deutschland

Sažetak

The molecular structures of 1-methyl-1-tert-butyl-cyclopropane and 1- methyl-l-iso-propyl-cyclopropane have been studied by gas-phase electron diffraction. The effects of hybridization and sterical overcrowding on the central C-C bond are discussed. Theoretical calculations (ab initio HF/6- 31G*; AM1;MM3) of the geometiy of a series of molecules of relevance for the problems treated, have been carried out.

Ključne riječi

Hrčak ID:

137285

URI

https://hrcak.srce.hr/137285

Datum izdavanja:

31.12.1991.

Posjeta: 1.138 *