Izvorni znanstveni članak

The Influence of f Orbitals on δ Metal Bonds

Li Ming ; Department of Chemistry, Southwest China Teachers University, Chongqing, People’s Republic of China
Shan Zion ; Department of Chemistry, Southwest China Teachers University, Chongqing, People’s Republic of China

Sažetak

Some 3 metal bonds have been studied by using the recently proposed population analysis based on hybrid orbitals. The results show that the 6 metal bonds are formed by overlap of the d-f hybrid orbitals of the metal atoms and that the f orbitals play an important role in the 6 bonds. Under the influence of the f orbitals on the 6 bonds, the densities of the 3 electrons between the metal atoms increase and their mean kinetic energies decrease. These are of importance to the stability in the S bonds.

Ključne riječi

Hrčak ID:

137323

URI

https://hrcak.srce.hr/137323

Datum izdavanja:

31.12.1991.

Posjeta: 834 *