Izvorni znanstveni članak
https://doi.org/10.13044/j.sdewes.2016.04.0004
Stabilization of Empty Fruit Bunch derived Bio-oil using Solvents
Chung Loong Yiin
; Biomass Processing Technology Cluster, Center for Biofuel and Biochemical Research, Chemical Engineering Department, Universiti Teknologi PETRONAS, 31750 Tronoh, Perak, Malaysia
Suzana Yusup
orcid.org/0000-0003-4790-3613
; Biomass Processing Technology Cluster, Center for Biofuel and Biochemical Research, Chemical Engineering Department, Universiti Teknologi PETRONAS, 31750 Tronoh, Perak, Malaysia
Mustakimah Mohamed
; Biomass Processing Technology Cluster, Center for Biofuel and Biochemical Research, Chemical Engineering Department, Universiti Teknologi PETRONAS, 31750 Tronoh, Perak, Malaysia
Parncheewa Udomsap
; National Metal and Materials Technology Center, 114 Thailand Science Park (TSP),
Boonyawan Yoosuk
; National Metal and Materials Technology Center, 114 Thailand Science Park (TSP), Phahonyothin Road, Khlong Nueng, Khlong Luang, Pathum Thani 12120, Thailand
Sittha Sukkasi
; National Metal and Materials Technology Center, 114 Thailand Science Park (TSP), Phahonyothin Road, Khlong Nueng, Khlong Luang, Pathum Thani 12120, Thailand
Sažetak
The intention of this research was to select the ideal condition for accelerated aging of bio-oil and the consequences of additive in stabilizing the bio-oil. The bio-oil was produced from the catalytic pyrolysis of empty fruit bunch. The optimum reaction conditions applied to obtain the utmost bio-oil yield were 5 wt% of H-Y catalyst at reaction temperature of 500 °C and nitrogen flow rate of 100 ml/min. A 10 wt% of solvents including acetone, ethanol, and ethyl acetate were used to study the bio-oil’s stability. All the test samples were subjected to accelerated aging at temperature of 80 °C for 7 days. The properties of samples used as the indicator of aging were viscosity and water content. The effectiveness of solvents increased in the following order: acetone, ethyl acetate, and 95 vol% ethanol. Based on the result of Gas Chromatography-Mass Spectrometry (GC-MS), it could impede the chain of polymerization by converting the active units in the oligomer chain to inactive units. The solvent reacted to form low molecular weight products which resulted in lower viscosity and lessen the water content in bio-oil. Addition of 95 vol% ethanol also inhibited phase separation.
Ključne riječi
Stabilization; Empty fruit bunch; Catalytic pyrolysis; Accelerated aging; Solvents; Gas Chromatography-Mass Spectrometry (GC-MS)
Hrčak ID:
150408
URI
Datum izdavanja:
31.3.2016.
Posjeta: 1.123 *