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Hybridization in MLk (k>2) Systems

Frank Liu ; Department of Chemistry, Central China Normal University, Wuhan, People's Republic of China
Chang-Guo Zhan ; Department of Chemistry, Central China Normal University, Wuhan, People's Republic of China

Sažetak

This paper describes a generalized and extended treatment of
the preceding papers in which the maximum overlap method was
employed but the results were limited by the. condition that the
number of Iigands surrounding the central atom should be two,
that is, k = 2 in molecule MLko Based on the special assumption.
that the angles < LpMLq = a between any two M-Lj bonds in
molecule MLk are equal, many general formula s related to the diagonal
matrix D (Jo), unitary matrix U", overlap matrix Sl and the bond strength F are derived. The properties of matrix SST are also discussed.

Ključne riječi

Hrčak ID:

175829

URI

https://hrcak.srce.hr/175829

Datum izdavanja:

25.2.1990.

Posjeta: 653 *