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Polarographic Behaviour of Some Potential Antineoplastic Benzothiazolylazopyrazoles

Rajeev Jain ; School of Studies in Chemistry, Jiwaji University, Gwalior - 474011,India
Anju Dixit ; School of Studies in Chemistry, Jiwaji University, Gwalior - 474011,India

Sažetak

The present paper summarises the electrochemical behaviour
of 4-benzothiazolylazo-N-thiocarbamoyl-3,5-dimethyl pyrazoles.
The reduction of above compounds takes place in a single 2e wave
at d.m.e. corresponding to the reduction of azo group. All the compounds give irreversible waves at pR values pR > 3.0 and
reversible waves at pR values pR < 3.0. All waves are diffusion
controlled and half-wave potentials pR dependent. The effect of
substituents has been determined quantitatively by the application
of Hammett equation. A plausible mechanism has been suggested
for the electrodeprocess. Furthermore, the effect of ionic-strength,
cations, anions and solvent composition has been studied in terms
of the changed electrical double layer.

Ključne riječi

Hrčak ID:

177277

URI

https://hrcak.srce.hr/177277

Datum izdavanja:

5.11.1986.

Posjeta: 751 *