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The Crystal Structure of (2,3,9,10-tetramethyl-1,4,8,11-tetraaza- 1,3,8, 10-cyclotetradecatetraene )copper(II) Tetraphenylborate

Andri E. Elia ; Department of Chemistry, BG-10, University of Washington, Seattle, Washington, 98195, U.S.A.
E. C. Lingafelter ; Department of Chemistry, BG-10, University of Washington, Seattle, Washington, 98195, U.S.A.
Verner Schomaker ; Department of Chemistry, BG-10, University of Washington, Seattle, Washington, 98195, U.S.A.

Sažetak

The crystal structure (P21/c, a = 1199.7(2), b = 1304.2(4), c =
= 1639.1(4) pm, beta = 102.10(1) 0 (J.. MoKa = 71.069 pm), Z = 2) of
this compound, [CuC14H24N4] [B(C5Hs)4]2, has been determined from
diffractometer x-ray data and refined by least-squares to R = 0.055
and Rw = 0.037.
The CuTIM cation, planar except for two methylene groups,
is one of the rare cases of planar four-coordinate copper(II),
although the apical regions of the coordination sphere are occupied
by the centers of phenyf groups from two tetraphenylborate ions.
The tetraphenylborate ion has a normal conformation which
deviates slightly, but significantly, from S4 symmetry.

Ključne riječi

Hrčak ID:

194134

URI

https://hrcak.srce.hr/194134

Datum izdavanja:

20.10.1984.

Posjeta: 865 *